NL Holdem Starting Hands,
Is there a website or guide that might help out newer people to hands which have better chances of hitting their cards on the flop/turn/river than other hands do...Or is this just with practice.
I don't understand what your question is. 27 is going to flop a pair as often as AK would; if that's what you mean by "chances of hitting their cards on the flop/turn/river".
